Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966458056> ?p ?o ?g. }
- W1966458056 endingPage "23" @default.
- W1966458056 startingPage "13" @default.
- W1966458056 abstract "The thermodynamics of the conversion of aqueous L-aspartic acid to fumaric acid and ammonia have been investigated using both heat conduction microcalorimetry and high-pressure liquid chromatography. The reaction was carried out in aqueous phosphate buffer over the pH range 7.25-7.43, the temperature range 13-43 degrees C, and at ionic strengths varying from 0.066 to 0.366 mol kg(-1). The following values have been found for the conversion of aqueous L-aspartateH- to fumarate2- and NH4+ at 25 degrees C and at zero ionic strength: K = (1.48 +/- 0.10) x 10(-3), DeltaG degrees = 16.15 +/- 0.16 kJ mol(-1), DeltaH degrees = 24.5 +/- 1.0 kJ mol(-1), and DeltaC(p) degrees = -147 +/- 100 J mol(-1) K(-1). Calculations have also been performed which give values of the apparent equilibrium constant for the conversion of L-aspartic acid to fumaric acid and ammonia as a function of temperature, pH and ionic strength." @default.
- W1966458056 created "2016-06-24" @default.
- W1966458056 creator A5006495049 @default.
- W1966458056 creator A5018714166 @default.
- W1966458056 creator A5030309928 @default.
- W1966458056 creator A5062847097 @default.
- W1966458056 date "1986-06-01" @default.
- W1966458056 modified "2023-10-16" @default.
- W1966458056 title "Thermodynamics of the conversion of aqueous l-aspartic acid to fumaric acid and ammonia" @default.
- W1966458056 cites W130220481 @default.
- W1966458056 cites W135750026 @default.
- W1966458056 cites W1585630458 @default.
- W1966458056 cites W1696303963 @default.
- W1966458056 cites W1883450768 @default.
- W1966458056 cites W1964429790 @default.
- W1966458056 cites W1968617772 @default.
- W1966458056 cites W2001478970 @default.
- W1966458056 cites W2032491813 @default.
- W1966458056 cites W2053212431 @default.
- W1966458056 cites W2065989760 @default.
- W1966458056 cites W2074642780 @default.
- W1966458056 cites W2079200601 @default.
- W1966458056 cites W2134814290 @default.
- W1966458056 cites W2322078320 @default.
- W1966458056 cites W2324100901 @default.
- W1966458056 cites W2330426000 @default.
- W1966458056 cites W2333639100 @default.
- W1966458056 cites W2342932171 @default.
- W1966458056 cites W2611176454 @default.
- W1966458056 cites W4250493997 @default.
- W1966458056 doi "https://doi.org/10.1016/0301-4622(86)85054-2" @default.
- W1966458056 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17007794" @default.
- W1966458056 hasPublicationYear "1986" @default.
- W1966458056 type Work @default.
- W1966458056 sameAs 1966458056 @default.
- W1966458056 citedByCount "5" @default.
- W1966458056 countsByYear W19664580562016 @default.
- W1966458056 countsByYear W19664580562022 @default.
- W1966458056 crossrefType "journal-article" @default.
- W1966458056 hasAuthorship W1966458056A5006495049 @default.
- W1966458056 hasAuthorship W1966458056A5018714166 @default.
- W1966458056 hasAuthorship W1966458056A5030309928 @default.
- W1966458056 hasAuthorship W1966458056A5062847097 @default.
- W1966458056 hasConcept C10710636 @default.
- W1966458056 hasConcept C121332964 @default.
- W1966458056 hasConcept C145148216 @default.
- W1966458056 hasConcept C147789679 @default.
- W1966458056 hasConcept C178790620 @default.
- W1966458056 hasConcept C179104552 @default.
- W1966458056 hasConcept C184651966 @default.
- W1966458056 hasConcept C185592680 @default.
- W1966458056 hasConcept C187428577 @default.
- W1966458056 hasConcept C2182769 @default.
- W1966458056 hasConcept C2776163829 @default.
- W1966458056 hasConcept C2776382133 @default.
- W1966458056 hasConcept C2781208047 @default.
- W1966458056 hasConcept C3288061 @default.
- W1966458056 hasConcept C45902088 @default.
- W1966458056 hasConcept C515207424 @default.
- W1966458056 hasConcept C55493867 @default.
- W1966458056 hasConcept C97355855 @default.
- W1966458056 hasConceptScore W1966458056C10710636 @default.
- W1966458056 hasConceptScore W1966458056C121332964 @default.
- W1966458056 hasConceptScore W1966458056C145148216 @default.
- W1966458056 hasConceptScore W1966458056C147789679 @default.
- W1966458056 hasConceptScore W1966458056C178790620 @default.
- W1966458056 hasConceptScore W1966458056C179104552 @default.
- W1966458056 hasConceptScore W1966458056C184651966 @default.
- W1966458056 hasConceptScore W1966458056C185592680 @default.
- W1966458056 hasConceptScore W1966458056C187428577 @default.
- W1966458056 hasConceptScore W1966458056C2182769 @default.
- W1966458056 hasConceptScore W1966458056C2776163829 @default.
- W1966458056 hasConceptScore W1966458056C2776382133 @default.
- W1966458056 hasConceptScore W1966458056C2781208047 @default.
- W1966458056 hasConceptScore W1966458056C3288061 @default.
- W1966458056 hasConceptScore W1966458056C45902088 @default.
- W1966458056 hasConceptScore W1966458056C515207424 @default.
- W1966458056 hasConceptScore W1966458056C55493867 @default.
- W1966458056 hasConceptScore W1966458056C97355855 @default.
- W1966458056 hasIssue "1" @default.
- W1966458056 hasLocation W19664580561 @default.
- W1966458056 hasLocation W19664580562 @default.
- W1966458056 hasOpenAccess W1966458056 @default.
- W1966458056 hasPrimaryLocation W19664580561 @default.
- W1966458056 hasRelatedWork W1966458056 @default.
- W1966458056 hasRelatedWork W1998569524 @default.
- W1966458056 hasRelatedWork W2024622110 @default.
- W1966458056 hasRelatedWork W2058912532 @default.
- W1966458056 hasRelatedWork W2065910533 @default.
- W1966458056 hasRelatedWork W2076766290 @default.
- W1966458056 hasRelatedWork W2089483114 @default.
- W1966458056 hasRelatedWork W2137824612 @default.
- W1966458056 hasRelatedWork W3022702319 @default.
- W1966458056 hasRelatedWork W2486184088 @default.
- W1966458056 hasVolume "24" @default.
- W1966458056 isParatext "false" @default.
- W1966458056 isRetracted "false" @default.
- W1966458056 magId "1966458056" @default.