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- W1966461657 abstract "Abstract The dipolar cycloaddition reactions of(α-oxyallyl)silanes 12a-g with 2,2-dimethylpropanenitrile oxide and benzonitrile oxide have been studied. Mixtures of anti (14a-g and 16a-g) and syn (15a-g and 17a-g) Δ2-isoxazolines are formed. The direction and magnitude of asymmetric induction depends on the allylie oxygen substituent: a free hydroxy provides a modest excess of the syn diastereomer, a silyl ether shows good selectivity for the anti diastereomer, and various acyl derivatives show low diastereoselectivity. The significance of these results is discussed in terms of two current models for asymmetric induction." @default.
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- W1966461657 date "1988-01-01" @default.
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- W1966461657 title "Asymmetric Induction in [3 + 2] Dipolar Cycloaddition Reactions of Nitrile Oxides with Chiral (α-Oxyallyl)silanes" @default.
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- W1966461657 doi "https://doi.org/10.1016/s0040-4020(01)86647-3" @default.
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