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- W1966479574 abstract "Cs11[(WN2,5O1,5)2](N3)2 entsteht als leicht hydrolysierendes, gelbes Pulver aus einem Eduktgemenge von CsNH2, W und WO3 bei 620 °C in Autoklaven. Es kristallisiert monoklin in der Raumgruppe C2/m mit den Gitterkonstanten a = 12,421(4) Å, b = 11,568(6) Å, c = 10,516(4) Å, β = 118,71(3)° und Z = 4. Die Kristallstruktur ist aus isolierten Tetraedern [WX4] aufgebaut (X = N, O), die von Caesiumionen verknüpft werden. Zwischen den Caesiumionen befinden sich von den Tetraedern [WX4] separierte Azidionen. Die Wolframatome und die Azidionen bilden gemeinsam das Motiv einer verzerrten Variante des CsCl-Strukturtyps. Synthesis and Structure of Cs11[(WN2,5O1,5)2](N3)2, a Cesium Oxo Nitrido Monotungstate(VI) Azide Cs11[(WN2,5O1,5)2](N3)2 results from the reaction of a mixture of CsNH2, W and WO3 at 620 °C in autoclaves. It crystallizes monoclinic in the space group C2/m with the lattice parameters a = 12.421(4) Å, b = 11.568(6) Å, c = 10.516(4) Å, β = 118.71(3)° and Z = 4. The crystal structure is built up by isolated tetrahedra [WX4] with X = N, O, which are connected by cesium cations. Between the cesium ions lie azide ions separated from the anions [WX4]. The tungsten atoms and azide ions together build up the motif of a distorted arrangement of the CsCl structure type." @default.
- W1966479574 created "2016-06-24" @default.
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- W1966479574 date "1999-07-01" @default.
- W1966479574 modified "2023-09-23" @default.
- W1966479574 title "Synthese und Struktur von Cs11[(WN2,5O1,5)2](N3)2, ein Caesiumoxonitridomonowolframat(VI)-azid" @default.
- W1966479574 doi "https://doi.org/10.1002/(sici)1521-3749(199907)625:7<1093::aid-zaac1093>3.0.co;2-r" @default.
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