Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966484533> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W1966484533 endingPage "2936" @default.
- W1966484533 startingPage "2924" @default.
- W1966484533 abstract "μ-(η 5 : η 5 -Fulvalene)-di-μ-hydrido-bis(η 5 -cyclopentadienyltitanium) and μ-(η 5 : η 5 -fulvalene)-μ-chloro-μ-hydrido-bis(cyclopentadienyltitanium) form a thermally stable complex which catalyzes the intermolecular hydrogen transfer in unsaturated hydrocarbons, in addition to isomerizations and cyclizations. Cyclic hydrocarbons disproportionate under catalysis to saturated and aromatic hydrocarbons, while linear olefins yield predominantly linear alkanes and high molecular weight tar. The catalyst enables the hydrocarbon system to approach the thermodynamic equilibrium through a series of substitution reactions between alkyl- and allyltitanocene-like species and olefins and dienes. The catalytic complex was characterized by UV and ESR spectra. About one half of overall titanium content could be converted to mononuclear η 3 -allyltitanocene-like species, stable up to 400 °C. This exceptional thermal stability is ascribed to a firmly bound allyl containing ligand." @default.
- W1966484533 created "2016-06-24" @default.
- W1966484533 creator A5023293724 @default.
- W1966484533 creator A5036669240 @default.
- W1966484533 creator A5042952795 @default.
- W1966484533 creator A5051291630 @default.
- W1966484533 creator A5061738046 @default.
- W1966484533 creator A5080627388 @default.
- W1966484533 date "1983-01-01" @default.
- W1966484533 modified "2023-10-18" @default.
- W1966484533 title "Intermolecular hydrogen transfer in unsaturated hydrocarbons induced by dimeric titanocene" @default.
- W1966484533 doi "https://doi.org/10.1135/cccc19832924" @default.
- W1966484533 hasPublicationYear "1983" @default.
- W1966484533 type Work @default.
- W1966484533 sameAs 1966484533 @default.
- W1966484533 citedByCount "5" @default.
- W1966484533 countsByYear W19664845332014 @default.
- W1966484533 crossrefType "journal-article" @default.
- W1966484533 hasAuthorship W1966484533A5023293724 @default.
- W1966484533 hasAuthorship W1966484533A5036669240 @default.
- W1966484533 hasAuthorship W1966484533A5042952795 @default.
- W1966484533 hasAuthorship W1966484533A5051291630 @default.
- W1966484533 hasAuthorship W1966484533A5061738046 @default.
- W1966484533 hasAuthorship W1966484533A5080627388 @default.
- W1966484533 hasConcept C116569031 @default.
- W1966484533 hasConcept C161790260 @default.
- W1966484533 hasConcept C166950319 @default.
- W1966484533 hasConcept C170493617 @default.
- W1966484533 hasConcept C178790620 @default.
- W1966484533 hasConcept C185592680 @default.
- W1966484533 hasConcept C188027245 @default.
- W1966484533 hasConcept C2777207669 @default.
- W1966484533 hasConcept C2780263894 @default.
- W1966484533 hasConcept C32909587 @default.
- W1966484533 hasConcept C55493867 @default.
- W1966484533 hasConcept C75473681 @default.
- W1966484533 hasConceptScore W1966484533C116569031 @default.
- W1966484533 hasConceptScore W1966484533C161790260 @default.
- W1966484533 hasConceptScore W1966484533C166950319 @default.
- W1966484533 hasConceptScore W1966484533C170493617 @default.
- W1966484533 hasConceptScore W1966484533C178790620 @default.
- W1966484533 hasConceptScore W1966484533C185592680 @default.
- W1966484533 hasConceptScore W1966484533C188027245 @default.
- W1966484533 hasConceptScore W1966484533C2777207669 @default.
- W1966484533 hasConceptScore W1966484533C2780263894 @default.
- W1966484533 hasConceptScore W1966484533C32909587 @default.
- W1966484533 hasConceptScore W1966484533C55493867 @default.
- W1966484533 hasConceptScore W1966484533C75473681 @default.
- W1966484533 hasIssue "10" @default.
- W1966484533 hasLocation W19664845331 @default.
- W1966484533 hasOpenAccess W1966484533 @default.
- W1966484533 hasPrimaryLocation W19664845331 @default.
- W1966484533 hasRelatedWork W1497930170 @default.
- W1966484533 hasRelatedWork W1973386006 @default.
- W1966484533 hasRelatedWork W1976131234 @default.
- W1966484533 hasRelatedWork W2002091057 @default.
- W1966484533 hasRelatedWork W2037504287 @default.
- W1966484533 hasRelatedWork W2041216868 @default.
- W1966484533 hasRelatedWork W2076932711 @default.
- W1966484533 hasRelatedWork W2523001587 @default.
- W1966484533 hasRelatedWork W2950046352 @default.
- W1966484533 hasRelatedWork W2952987296 @default.
- W1966484533 hasVolume "48" @default.
- W1966484533 isParatext "false" @default.
- W1966484533 isRetracted "false" @default.
- W1966484533 magId "1966484533" @default.
- W1966484533 workType "article" @default.