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• W1966495890 endingPage "2015" @default.
• W1966495890 startingPage "2015" @default.
• W1966495890 abstract "We report the design and synthesis of two porous graphene frameworks (PGFs) prepared via covalent functionalization of reduced graphene oxide (RGO) with iodobenzene followed by a C-C coupling reaction. In contrast to RGO, these 3D frameworks show high surface area (BET, 825 m(2) g(-1)) and pore volumes due to the effect of pillaring. Interestingly, both the frameworks show high CO2 uptake (112 wt% for PGF-1 and 60 wt% for PGF-2 at 195 K up to 1 atm). PGFs show nearly 1.2 wt% H2 storage capacity at 77 K and 1 atm, increasing to ∼1.9 wt% at high pressure. These all carbon-based porous solids based on pillared graphene frameworks suggest the possibility of designing related several such novel materials with attractive properties." @default.
• W1966495890 created "2016-06-24" @default.
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• W1966495890 date "2014-01-01" @default.
• W1966495890 modified "2023-10-13" @default.
• W1966495890 title "Porous graphene frameworks pillared by organic linkers with tunable surface area and gas storage properties" @default.
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• W1966495890 doi "https://doi.org/10.1039/c3cc46907g" @default.
• W1966495890 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24412955" @default.
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