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- W1966497735 abstract "X-Ray diffraction study of two copper-exchanged Y zeolites (Cu16Na24Y and Cu12Na5H27Y) in the dehydrated state showed that the cupric ions strongly prefer SI sites in the sodalite cages where they are firmly bonded to three framework oxygen atoms. The effect of sorbed molecules on the cation distribution was studied by adding ammonia, pyridine, naphthalene and butene to the dehydrated zeolite. Adsorption of a small amount of ammonia which can enter the sodalite cages produced slight but significant changes in the copper position. Addition of pyridine, naphthalene or butene induced an important migration of copper ions from SI and SI sites to the supercages where they can interact with sorbed molecules. The nature of the cation-organic molecule associations was investigated: infrared measurements and X-ray results provided evidence of a proton transfer from the organometallic complexes to the framework oxygen atoms." @default.
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- W1966497735 date "1972-09-01" @default.
- W1966497735 modified "2023-10-18" @default.
- W1966497735 title "X-ray diffraction study of cupric ion migrations in two Y-type zeolites containing adsorbed reagents" @default.
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- W1966497735 doi "https://doi.org/10.1016/0021-9517(72)90087-5" @default.
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