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- W1966500273 abstract "A novel intermolecular [4 + 3] cycloaddition method to construct 1,4-dioxide seven-membered oxacycles was developed. This one-step method was carried out in the presence of catalytic amount of (C2H5)2OBF3 under mild conditions. Seven-membered oxacycles and some natural compounds could be easily synthesized via this protocol. Control experiments were carried out and possible mechanism for the reaction was proposed. Asymmetric reactions were proceeded and 3e was obtained with moderate ee value." @default.
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- W1966500273 date "2010-12-30" @default.
- W1966500273 modified "2023-10-16" @default.
- W1966500273 title "[4 + 3] Cycloaddition of Aromatic α,β-Unsaturated Aldehydes and Ketones with Epoxides: One-Step Approach to Synthesize Seven-Membered Oxacycles Catalyzed by Lewis Acid" @default.
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- W1966500273 doi "https://doi.org/10.1021/jo101669t" @default.
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