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- W1966528752 abstract "The isomerization of enol acetate epoxides by zinc bromide leads to ketoacetates with retention of configuration. Thermal isomerization yields a ketoacetate with inversion of the configuration by a concerted mechanism if the oxirane does not contain a hydrogen atom. In the case of an oxirane containing hydrogen, an 'acid' type mechanism competes favorably with the concerted mechanism; the former yields a ketoacetate with retention of configuration. The isomer in which the configuration is retained is not the most stable. [Journal translation]" @default.
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- W1966528752 date "1975-03-01" @default.
- W1966528752 modified "2023-10-14" @default.
- W1966528752 title "Isomérisation d'époxydes d'acétates d'énols en série pinanique" @default.
- W1966528752 doi "https://doi.org/10.1139/v75-103" @default.
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