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- W1966531873 abstract "In the first part of our electrochemical (cyclic voltammetric) study of montmorillonite-modified electrodes, results about film permeability have been presented. The structure of the porous aerogel–hydrogel and the effect of layer-thickness have been discussed. The more compact structure and less permeable Na- and H-montmorillonite result in smaller peak currents characteristic of the permeability of the clay film, than with more permeable Ca-montmorillonite. The thicker the film the less organized the structure and the value of the peak current decreases at increasing thickness.The kinetics of the hydration–dehydration, swelling–shrinking (“break-in/leach-out”) processes and the effect of hydrophobization were demonstrated, too. Kinetical measurement data provide information about diffusional transport via macro, meso-, and micropores, and thus characterize pore structure. Permeability decreases with increasing extents of hydrophobization. The rate constants of structure-dependent macro- and microdiffusion have been calculated." @default.
- W1966531873 created "2016-06-24" @default.
- W1966531873 creator A5039390814 @default.
- W1966531873 date "2003-11-01" @default.
- W1966531873 modified "2023-09-26" @default.
- W1966531873 title "Electrochemical permeability measurements of hydrophilic and hydrophobized montmorillonite films" @default.
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- W1966531873 doi "https://doi.org/10.1016/j.colsurfa.2003.07.003" @default.
- W1966531873 hasPublicationYear "2003" @default.
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