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• W1966532968 abstract "The catalytic activities of pure and mixed catalysts of alkali and transition metal salts in steam-char gasification at 700–850°C were measured with a thermobalance. The effects of catalyst loading (0–35 wt%) and composition, coal rank and steam partial pressure were determined. The initial rate increases with increasing steam partial pressure in non-catalytic gasification but is almost independent of it in catalytic gasification. The catalytic activities of single salts are in the order K2CO3 > Ni(NO3)2 > K2SO4 ≈ Ba(NO3)2 > FeSO4. The gasification rate with K2SO4 can be enhanced by addition of other salts and the order of catalytic activity of the salt mixtures tested is K2SO4 + Ni(NO3)2 > K2SO4 + Ba(NO3)2 ≈ K2SO4 + FeSO4. The char reactivity increases with increasing catalyst loading for K2SO4 + Ni(NO3)2 and with gasification temperature. The catalytic effectiveness of K2SO4 + Ni(NO3)2 decreases with increasing coal rank. An equimolar mixture of K2SO4 and Ni(NO3)2 exhibits the highest catalytic activity and a synergistic effect." @default.
• W1966532968 created "2016-06-24" @default.
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• W1966532968 date "1995-09-01" @default.
• W1966532968 modified "2023-10-12" @default.
• W1966532968 title "Catalytic activity of alkali and transition metal salt mixtures for steam-char gasification" @default.
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• W1966532968 doi "https://doi.org/10.1016/0016-2361(95)00081-f" @default.
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