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• W1966554989 abstract "A vanadyl pyrophosphate (VPO) catalyst was investigated for its sequential reduction and oxidation ability for butane oxidation, using a novel oscillating microbalance reactor. Correlation of the redox kinetics with the identities of the vanadium species obtained by potentiometric titration methods suggests that only the near-surface oxygen is readily available for the oxidation of butane; effective redox cycles can only occur between V5+ and V4+; accumulation of V3+ species represents one mode of catalyst deactivation." @default.
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• W1966554989 date "2000-07-01" @default.
• W1966554989 modified "2023-10-12" @default.
• W1966554989 title "Identification of vanadium species involved in sequential redox operation of VPO catalysts" @default.
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• W1966554989 doi "https://doi.org/10.1016/s0926-860x(00)00439-7" @default.
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