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- W1966555789 abstract "Several new zeolites have been synthesized in which either part or all of the alumina (Al2O3) has been replaced by gallia (Ga2O3). Some of these crystalline products have the adsorptive properties of molecular sieves. The preparation of a pure gallia sieve with the 13X (alumina sieve) structure involves some marked changes in several reaction variables. The gallia sieve is entirely analogous to the alumina sieve, in X-ray powder pattern, composition, and adsorptive capacity. The preparation of the gallium analogue of sodalite is also reported along with another new gallio-silicate with no known alumina counterpart. Partial replacement of alumina by gallia has been affected by several different routes with the weight per cent gallia ranging from 7 to 20, the latter representing a 1:1 mole ratio of gallia to alumina in the product. These “mixed” sieves show very good adsorptive properties also." @default.
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- W1966555789 date "1961-12-01" @default.
- W1966555789 modified "2023-10-17" @default.
- W1966555789 title "Preparation of gallium-containing molecular sieves" @default.
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- W1966555789 doi "https://doi.org/10.1016/0022-1902(61)80271-6" @default.
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