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- W1966559615 abstract "The first example of the p-orbital overlap controlled enantioselectivity of Norrish type II photocyclization reaction was described. Irradiation of 5-methyl bicyclo[1.1.1]pentanyl ketone with UV in the solid state as well as in the acetonitrile solution afforded the Norrish/Yang photocyclization compound as the sole product. Solid-state asymmetric photochemical studies using ionic chiral auxiliary technique led to the enantioselectivity as high as 60%. The results were rationalized by X-ray single crystal structure." @default.
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- W1966559615 date "2012-01-01" @default.
- W1966559615 modified "2023-10-05" @default.
- W1966559615 title "Photochemical Studies on 5-Methylbicyclo[1.1.1]pentane Derivatives: p-Orbital Overlap Controlled Enantioselectivity" @default.
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- W1966559615 doi "https://doi.org/10.1002/cjoc.201100083" @default.
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