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• W1966574148 abstract "This work addresses a detailed procedure of the application of previously developed equation of state (EOS) to estimate liquid densities of pure ionic liquids (ILs) containing tetrafluoroborate and hexafluorophosphate anions as a function of temperature and pressure. Besides, the present EOS is successfully extended to binary mixtures IL + water, IL + DMSO, IL + ethanol, IL + methanol, IL + 1-propanol, and IL + tetrahydrofuran (THF) to compute their mixture density and excess volumes. In this study, our focus is on improving the previous EOS through a reparametrization procedure. Moreover, we have demonstrated the density behavior of studied ILs in terms of alkyl chain length of imidazolium cation and the anion size via proposed model. The accuracies of our calculations are of the order of ± 3%. The average absolute deviation (AAD) of the calculated densities of pure ILs for 962 examined data points was found to be 1.55%. Finally, the AAD for the mixture densities for 665 examined data points was found to be 0.58%." @default.
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• W1966574148 date "2011-05-01" @default.
• W1966574148 modified "2023-09-23" @default.
• W1966574148 title "Modeling the volumetric properties of mixtures involving ionic liquids using perturbed hard-sphere equation of state" @default.
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• W1966574148 doi "https://doi.org/10.1016/j.molliq.2011.02.007" @default.
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