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• W1966584712 endingPage "2017" @default.
• W1966584712 startingPage "2011" @default.
• W1966584712 abstract "Four novel mixed metal selenites or tellurites containing PdO4 squares, namely, BaPd(SeO3)2, Bi2Pd(SeO3)4, and Pb2Pd(QO3)2Cl2 (Q = Se, Te), have been prepared and structurally characterized by single crystal X-ray diffraction analyses. These compounds exhibit three different types of anionic structures. BaPd(SeO3)2 contains one-dimensional (1D) [Pd(SeO3)2]2− anionic chains composed of PdO4 units linked by SeO32−groups in a bidentate bridging fashion. Bi2Pd(SeO3)4 exhibits a complicated 3D architecture constructed by [Bi(SeO3)]+ and [Pd(SeO3)2]2− layers that are alternating along the a-axis. The [Pd(SeO3)2]2− layers are composed of Pd2+ ions bridged by SeO32− anions in a bidentate fashion. Pb2Pd(QO3)2Cl2 (Q = Se, Te) features zero-dimensional (0D) [Pd(QO3)Cl2]4− (Q = Se, Te) anionic clusters, which are further bridged by Pb2+ cations into a 3D network. The results of optical diffuse-reflectance spectrum measurements and band structure calculations based on DFT methods indicate that all the compounds are wide-band-gap semiconductors." @default.
• W1966584712 created "2016-06-24" @default.
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• W1966584712 date "2012-01-01" @default.
• W1966584712 modified "2023-10-16" @default.
• W1966584712 title "New mixed metal selenites and tellurites containing Pd²⁺ions in a square planar geometry" @default.
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• W1966584712 doi "https://doi.org/10.1039/c1dt11836f" @default.
• W1966584712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22175062" @default.
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