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• W1966585364 abstract "Itaconic acid and some of its derivates were hydrogenated with sol–gel entrapped Rh/BPPM catalysts in methanol solutions. The immobilization process was carried out by different gel building agents: hydrophilic tetramethyl orthosilicate Si(OMe)4 (TMOS) and tetraethyl orthosilicate Si(OEt)4 (TEOS), hydrophobic triethoxyphenylsilane PhSi(OEt)3/TMOS and trimethoxy(octyl)silane OcSi(OMe)3/TMOS. The choice of the silane precursor influences the enantioselectivity and the rate of the reaction because of the hydrophobic interactions between catalyst, gel and substrate. The immobilized catalyst could be recovered and recycled several times under N2-atmosphere. About 90–99% ee were achieved for the hydrogenation of itaconic acid to (S)-(+)-2-methyl succinic acid, and about 14% ee for the hydrogenation of dimethylitaconate to (S)-(+)-2-methyl-succinic acid dimethylester." @default.
• W1966585364 created "2016-06-24" @default.
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• W1966585364 date "2013-01-01" @default.
• W1966585364 modified "2023-10-18" @default.
• W1966585364 title "Enantioselective hydrogenation of itaconic acid and its derivates with sol–gel immobilized Rh/BPPM catalysts" @default.
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• W1966585364 doi "https://doi.org/10.1016/j.molcata.2012.10.016" @default.
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