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- W1966592034 abstract "The successive formation of complexes MA+ and MA2 of alkaline-earth cations M2+ with lasalocid HA is observable in methanol. Knowing the corresponding formation constants, it was possible to access NMR parameters specific to these two types of species for the four alkaline-earth cations. 13C and 1H chemical shifts are reported for MA+ and MA2; 1H–1H coupling constants for MA+ only. Experiments at low temperature and experiments using the paramagnetic cation Mn2+ determined the coordination sites. All these data show an appreciable variability of coordination in the series of alkaline-earth cations. Computations using the semi-empirical quantum methods AM1 and PM3 and Monte-Carlo simulations in methanol according to BOSS, mainly on MgA+ and BaA+ fully confirmed these findings." @default.
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- W1966592034 date "1995-01-01" @default.
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- W1966592034 title "Interactions between metal cations and the ionophore lasalocid. Part 13. Structure of 1:1 and 2:1 lasalocid anion–divalent cation complexes in methanol" @default.
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- W1966592034 doi "https://doi.org/10.1039/p29950001939" @default.
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