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- W1966598753 abstract "The Born model is frequently used for calculating the work of solvation or free energy of ion–solvent interactions. The original Born equation does not reproduce the experimental data on solvation free energy, possibly due to the fact that the model does not take in account the changes in the structure of solvent in presence of an ion. The model also fails to account certain other experimental observations. A new derivation of the model is presented assuming the changes in the structure of solvent being analogous to surface phenomena. In addition to the successful checking its validity against experimental data, the revised expression can also yield the generalized Dupre rule for surface effects. Significance of new terms and their impact in accounting observed trends are discussed." @default.
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- W1966598753 date "1994-12-01" @default.
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- W1966598753 title "Surface Effects in the Born Solvation Model" @default.
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- W1966598753 doi "https://doi.org/10.1246/bcsj.67.3150" @default.
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