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• W1966612107 abstract "When an electrode is immersed for the first time into an electrolyte solution under conditions such that no charge transfer is allowed through its interface, it comes to a state of zero electronic charge of its electrical double layer. Therefore, the immersion potential (IP) measured vs. a reference electrode at open circuit mode, should correspond to the potential of zero charge (pzc). It is shown that the value of the IP reflects the state of oxidation of the electrode surface prior to wetting with the solution. This has been verified experimentally. The dielectric constant ε of the dielectrically saturated solvent layer close to the electrode surface was estimated by comparing the change of experimental values of the IP with the calculated change in surface polarization obtained after a surface chemical treatment (hydrogen chemisorption). The value obtained, 5.4±1.4, falls within the range 5–10 estimated by using different approaches." @default.
• W1966612107 created "2016-06-24" @default.
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• W1966612107 date "1983-06-01" @default.
• W1966612107 modified "2023-09-26" @default.
• W1966612107 title "The immersion potential of high surface electrodes" @default.
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• W1966612107 doi "https://doi.org/10.1016/s0022-0728(83)80398-2" @default.
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