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• W1966672364 abstract "We examine field-induced charge-carrier separation at doped organic/organic heterointerfaces consisting of tetrafluorotetracyanoquinodimethane doped $4,{4}^{ensuremath{'}},{4}^{ensuremath{''}}$-tris($N$-1-naphtyl-$N$-phenylamino)-triphenylamine as hole-transporting layer and Li-doped 1,3,5-tri(phenyl-2-benzimidazole)-benzene as electron-transporting layer. Low-temperature $Itext{ensuremath{-}}V$ characteristics, thickness-dependent $Itext{ensuremath{-}}V$ characteristics, and Kelvin probe measurements are used to model the energy-level alignment at the interface. No explicit temperature dependence is observed. Thickness-dependent $Itext{ensuremath{-}}V$ characteristics and Kelvin probe measurements give evidence for a $5text{ensuremath{-}}mathrm{nm}$-thin depletion layer adjacent to the interface. Consistent with our experimental results, we propose a model of electrons tunneling through the depletion zone from the highest occupied molecular orbit of the hole-transporting material to the lowest unoccupied molecular orbit of the electron-transporting material. This generates an electron-hole pair, which dissociates under the intense electric field close to the interface." @default.
• W1966672364 created "2016-06-24" @default.
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• W1966672364 date "2007-06-19" @default.
• W1966672364 modified "2023-10-17" @default.
• W1966672364 title "Temperature-independent field-induced charge separation at doped organic/organic interfaces: Experimental modeling of electrical properties" @default.
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• W1966672364 doi "https://doi.org/10.1103/physrevb.75.235321" @default.
• W1966672364 hasPublicationYear "2007" @default.
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