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- W1966677148 abstract "Three camphor-based tertiary-amido isoborneols have been obtained from ketopinic acid and tested as ligands for the hydroxyamide-catalyzed enantioselective addition of diethylzinc to benzaldehyde in the absence of Ti(O-i-Pr)4. The results obtained have been compared with previous results published by Oppolzer. The new chiral ligands showed effective asymmetric activity in the absence of titanium (up to 98% yield and 90% ee). It is demonstrated that non-bulky dialkylamino groups are necessary for obtaining high chemical yields, whereas the C2 symmetry is necessary to reach a good enantioselection level." @default.
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- W1966677148 date "2008-04-01" @default.
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- W1966677148 title "Hydroxyamide-catalyzed enantioselective addition of diethylzinc to benzaldehyde in the absence of titanium" @default.
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- W1966677148 doi "https://doi.org/10.1016/j.tetasy.2008.02.025" @default.
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