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• W1966681306 abstract "We report on a novel covalent coupling method using electrochemical activation of hydroquinone monoester self-assembled monolayers. The reaction generates benzoquinone as a good leaving group, followed by nucleophilic acyl substitution with a primary amine to form an amide in high yield. The method allows the site-selective and the reaction-controlled positioning of biotin on the individually addressable microelectrode array and, subsequently, density-differentiated patterning of streptavidin on the biotin surfaces. Because the electrochemical coupling method provides a very rapid, mild, and quantitatively controllable reaction pathway for covalent bond formation on organic surfaces, it will be used as a versatile molecular anchoring tool in fields such as molecular electronics and biochip technology." @default.
• W1966681306 created "2016-06-24" @default.
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• W1966681306 date "2004-04-13" @default.
• W1966681306 modified "2023-10-13" @default.
• W1966681306 title "Electrochemically Induced and Controlled One-Step Covalent Coupling Reaction on Self-Assembled Monolayers" @default.
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• W1966681306 doi "https://doi.org/10.1021/la036350r" @default.
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• W1966681306 hasPublicationYear "2004" @default.
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