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- W1966681785 abstract "It is well known that for certain photoelectrochemical cells, the flat-band voltage calculated from the photocurrent onset is actually false and can differ from the true flat-band voltage by several hundred millivolts. We have observed this phenomenon for the cadmium selenide/aqueous polysulfide, as well as for other photoelectrochemical cells. In addition, we have observed a phase shift in the photocurrent signal at the voltage where the false onset occurs and we attribute this shift to the electronic filling of surface states. A kinetic model is used in conjunction with an equivalent circuit in order to verify this hypothesis. Results of the theoretical model agree satisfactorily with experimental data. Experimental guidelines for increasing the reliability of photocurrent onset measurements are presented." @default.
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- W1966681785 date "1984-11-15" @default.
- W1966681785 modified "2023-09-26" @default.
- W1966681785 title "Investigation into the photocurrent quadrature signal of photoelectrochemical cells" @default.
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- W1966681785 doi "https://doi.org/10.1063/1.333833" @default.
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