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- W1966684682 abstract "Abstract The compounds bis(diorganomonothiophosphinato)trimethylantimony(V), Me 3 Sb(OSPR 2 ) 2 , where R = Me, Et and Ph, have been prepared and characterized by IR, multinuclear ( 1 H, 13 C, 31 P) NMR spectroscopy and mass spectrometry. The structure of Me 3 Sb(OSPPh 2 ) 2 has been determined by single-crystal X-ray diffraction. The crystal consists of discrete monomers. In the molecule there is a trigonal bipyramidal environment around antimony, with the two monothio ligands bound to the metal only through oxygen atoms (SbO(1), 2.107(5) A; SbO(2), 2.114(5) A. The antimony—sulphur distances, i.e. 3.924 and 3.998 A, are consistent with non-bonding van der Waals contacts ( ca. 4.0 A). The average bond distances within the phosphorus ligand are PO = 1.552, PS = 1.945 and PC = 1.808 A. The SbC 3 unit is planar, and the angle between the axial SbO bonds is 177.7(2)°. Coordination of the monothiophosphinato ligand in monodentate mode is unusual; such ligands usually exhibit chelate or bridging coordination through both oxygen and sulphur atoms." @default.
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- W1966684682 date "1994-04-01" @default.
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- W1966684682 title "Trimethylantimony(V) diorganomonothiophosphinates: the crystal structure of bis(diphenylmonothiophosphinato)trimethylantimony(V), Me3Sb(OSPPh2)2, containing a monodentate monothiophosphinato ligand" @default.
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- W1966684682 doi "https://doi.org/10.1016/0022-328x(94)80038-3" @default.
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