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- W1966690149 abstract "The title salts formula Rh(Me2NCS2(RNC)2(TCNQ) and Rh(EtO)2PS2(RNC)2(TCNQ) (R = Ph, 4-MeC6H4, and 4-MeOC6H4 were prepared. The binding energies pf Rh 3d32 and 3d52 electrons obtained from X-ray photoelectron spectra of these salts fall between those of RhIL(RNC)2 and RhIIIL(RNC)2I2, and are almost the same as those of the TCNE salts, RhL(RNC)2(TCNE) (L = Me2NCS2 and (EtO)2PS2. These results, in addition to electronic absorption and ESR spectra, suggest that the TCNQ salts involve the Rh(II) species and the TCNQ⨪ radical anion and that the Rh(II) species exist as dimes with the Rh(II)Rh(II) bonding in the solid state. All the TCNQ salts behave as the semi-conductors in the 202̄90°C range, although the electrical resistivities are large (107–1011 Ω cm at 298 K as compacted samples)." @default.
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- W1966690149 date "1983-01-01" @default.
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- W1966690149 title "Synthesis of TCNQ salts with dithiocarbamato- and dithiophosphatobis-(aryl isocyanide)rhodium(I) and their spectroscopic and electrical properties" @default.
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- W1966690149 doi "https://doi.org/10.1016/s0020-1693(00)83568-9" @default.
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