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- W1966696595 abstract "Dialkyl phenylphosphonite PhP(OR)2 (R = Et, Me) undergoes an intramolecular Arbuzov rearrangement upon electrolysis at an anode in acetonitrile under an oxygen atmosphere to yield alkyl alkylphenylphosphinate PhRP(=O)(OR). The results here suggest that the rearrangement takes place through a radical-chain mechanism initiated by anodic oxidation of the phosphonite to the corresponding cation radical." @default.
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- W1966696595 date "1996-03-01" @default.
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- W1966696595 title "An intramolecular Arbuzov rearrangement initiated by anodic oxidation" @default.
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- W1966696595 doi "https://doi.org/10.1016/0040-4039(96)00072-x" @default.
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