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• W1966700129 abstract "Abstract Using 1 H and 13 C NMR spectra, PFG NMR self-diffusion measurements, 1 H and 13 C NMR relaxations and 1 H NOESY NMR spectra, FTIR spectra and quantum-chemical DFT and MP2 calculations, the interaction of 1,2-dimethoxyethane (DME) with water (W) was re-examined. It was confirmed that, primarily, one W molecule forms two O···H hydrogen bonds with DME in tgt conformation. At medium and higher W contents, however, larger hydrates of DME are formed, predominantly with five W molecules. The compact structure of the hydrate is warranted by O⋯H hydrogen bonds, some of them perceptibly tighter than those in the primary hydrate, and by non-classical CH 3 ⋯O hydrogen bonds." @default.
• W1966700129 created "2016-06-24" @default.
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• W1966700129 date "2011-04-01" @default.
• W1966700129 modified "2023-09-24" @default.
• W1966700129 title "Hydration modes of an amphiphilic molecule 2: NMR, FTIR and theoretical study of the interactions in the system water–1,2-dimethoxyethane" @default.
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• W1966700129 doi "https://doi.org/10.1016/j.chemphys.2011.03.008" @default.
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