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- W1966705955 abstract "The average frequency of the uncoupled Raman OD stretching spectrum is always higher than that of glassy water for all the glassy aqueous electrolyte solutions investigated. Inorganic ions are usually classified as structure makers or structure breakers according to the viscosity B -coefficients of their aqueous solutions at ordinary temperature. Structure-making ions enhance the hydrogen bond strength while structure-breaking ones weaken the hydrogen bonds in aqueous solution. We here show that even structure-making ions (assigned by their viscosity B -coefficients at ordinary temperature) become a structure breaker in the sense that they weaken the hydrogen bonds in aqueous solution at low temperatures when we compare the strength of hydrogen bonds with that for glassy water." @default.
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- W1966705955 date "2006-08-01" @default.
- W1966705955 modified "2023-09-26" @default.
- W1966705955 title "Structure-making ions become structure breakers in glassy aqueous electrolyte solutions" @default.
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- W1966705955 doi "https://doi.org/10.1016/j.cplett.2006.06.055" @default.
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