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• W1966708758 abstract "A novel solid-state deuteron NMR method for spectroscopic imaging is presented. It employs information about molecular orientation and dynamics obtained from broad 2H-NMR lineshapes governed by the anisotropic quadrupole interaction without sacrificing spatial resolution. To this end, double-quantum coherence is created, which is independent of the strength of the quadrupole coupling. In a Fourier-imaging scheme magnetic-field gradients are applied for spatial encoding during the evolution of double-quantum coherence. In the detection period single-quantum coherence is recorded, providing a spectroscopic dimension with a wide-line spectrum. Its lineshape contains spatially resolved information about molecular orientation and dynamics. Experimental results are presented for orientation imaging of drawn polyethylene and molecular-dynamics imaging in a composite sample of glassy polystyrene and glassy polycarbonate, where the two species can be discriminated based on both the NMR lineshape and the spin-lattice relaxation time T 1." @default.
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• W1966708758 date "1990-10-20" @default.
• W1966708758 modified "2023-10-10" @default.
• W1966708758 title "Deuteron double-quantum NMR imaging of molecular order and mobility in solid polymers" @default.
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• W1966708758 doi "https://doi.org/10.1080/00268979000101921" @default.
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