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- W1966730479 abstract "Three new cluster-based cobalt/carboxylate frameworks, formulated as {[H3O][CoII7(μ3-OH)3(MeO-ip)6(H2O)3]·4.5H2O}n (1), {[CoII6(μ3-OH)2(But-ip)4(But-Hip)2(H2O)2]·2CH3CN}n (2), and {[CoII5(Me-ip)4(Me-Hip)2(H2O)4]·6H2O}n (3) (MeO-H2ip = 5-methoxyisophthalic acid, But-H2ip = 5-tert-buthylisophthalic acid, and Me-H2ip = 5-methylisophthalic acid) have been synthesized by the hydro(solvo)thermal reactions of Co2(CO)8 with the corresponding isophthalic acids in CH3CN, PriOH, and water. Single-crystal X-ray diffraction studies reveal that 1 and 2 both exhibit a three-dimensional (3D) pcu net based on hepta- and hexanuclear cobalt hydroxyl clusters {CoII7(μ3-OH)3} and {CoII6(μ3-OH)2}, respectively. Compound 3 is a 3D porous framework with an eight-connected bcu topology constructed from a pentanuclear cobalt cluster. It has been found that the structures of cobalt clusters in these compounds largely depend on the substituents on isophthalic acids. The magnetic studies indicate that both 1 and 2 show spin-canting antiferromagnetism, while 3 exhibits a magnetocaloric effect (MCE). The resulting entropy change of 3 is 13.23 J kg–1 K–1 for ΔH = 80 kG at 4 K." @default.
- W1966730479 created "2016-06-24" @default.
- W1966730479 creator A5007783109 @default.
- W1966730479 creator A5031175042 @default.
- W1966730479 creator A5091213060 @default.
- W1966730479 date "2013-07-17" @default.
- W1966730479 modified "2023-09-24" @default.
- W1966730479 title "Three New Three-Dimensional Frameworks Based on Hepta-, Hexa-, and Pentanuclear Cobalt Clusters Derived from Substituted Isophthalic Acids: Synthesis, Structures, and Magnetic Properties" @default.
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- W1966730479 doi "https://doi.org/10.1021/cg4007789" @default.
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