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• W1966734269 abstract "A bridged two-vial system aminocarbonylation protocol where Mo(CO)6 functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the Mo(CO)6-mediated and palladium(0)-catalyzed conversion to benzamides, while the identical one-vessel protocol afforded extensive reduction of the nitro functionality. The above-mentioned bridged two-compartment protocol furnished good results with both primary amines and secondary amines and sluggish aniline nucleophiles at 65–85 °C reaction temperatures." @default.
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• W1966734269 date "2012-12-12" @default.
• W1966734269 modified "2023-09-27" @default.
• W1966734269 title "Aminocarbonylations Employing Mo(CO)₆ and a Bridged Two-Vial System: Allowing the Use of Nitro Group Substituted Aryl Iodides and Aryl Bromides" @default.
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• W1966734269 doi "https://doi.org/10.1021/jo302322w" @default.
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