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• W1966736442 endingPage "9089" @default.
• W1966736442 startingPage "9085" @default.
• W1966736442 abstract "Simple silver(I) slats were found to be highly efficient and selective catalyst for carboxylative coupling of aryl- or alkyl-substituted terminal alkynes, CO2, and various allylic, propargylic or benzylic chlorides to exclusively yield functionalized 2-alkynoates. The activity is about 300 times that of the previously reported N-heterocyclic carbene copper(I) catalytic system. The ligand-free silver(I) catalytic system showed the wide generality of substrates involving both functionalized terminal alkynes and chloride compounds." @default.
• W1966736442 created "2016-06-24" @default.
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• W1966736442 date "2012-11-01" @default.
• W1966736442 modified "2023-10-06" @default.
• W1966736442 title "Ligand-free Ag(I)-catalyzed carboxylative coupling of terminal alkynes, chloride compounds, and CO2" @default.
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• W1966736442 doi "https://doi.org/10.1016/j.tet.2012.08.053" @default.
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