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- W1966745191 abstract "The dearomatization reaction of benzylic chlorides (1a−k), chloromethylnaphthalenes (1l−r), and naphthalene allyl chlorides (3a−d) with allenyltributyltin proceeded smoothly in the presence of Pd(PPh3)4 catalyst at room temperature to give the corresponding propargylated and/or allenylated dearomatization products (5, 5′; 6, 6′; and 7, respectively) in high to fair yields. The reaction of 1a−k proceeded smoothly in the presence of TBAF, whereas it was not necessary to use TBAF as an additive in the reactions of 1l−k and 3a−d. These reactions provided a new and efficient method for the synthesis of propargylic and allenic carbocycles." @default.
- W1966745191 created "2016-06-24" @default.
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- W1966745191 date "2010-03-24" @default.
- W1966745191 modified "2023-09-29" @default.
- W1966745191 title "Propargylic and Allenic Carbocycle Synthesis through Palladium-Catalyzed Dearomatization Reaction" @default.
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- W1966745191 doi "https://doi.org/10.1021/jo100211d" @default.
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