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- W1966756719 abstract "The uranium carbonitrides reacted with 6 M HCl or 6 M H2SO4 to yield primarily CH4, H2, NH4+, and either U4+ or U(SO4)2·4H2O. At 80°C, UN0·77C0·23 was inert in water, but UC0·68N0·25 hydrolyzed to CH4, H2, NH4+, and UO2. Uranium mononitride reacted with 0·5–15·8 M HNO3 producing a yellow uranyl nitrate solution, N2, nitrogen oxides, HNO2, and, under some conditions, NH4+. The uranium carbonitrides reacted exothermally with nitric acid, yielding the same products that were obtained with uranium mononitride, as well as CO2, unidentified nitric acid-soluble organic compound(s), and, in some cases, black organic residues. Ammonium ion was an intermediate in the oxidation of nitride or carbonitride nitrogen to N2." @default.
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- W1966756719 date "1967-06-01" @default.
- W1966756719 modified "2023-09-26" @default.
- W1966756719 title "Reactions of uranium and thorium carbides with aqueous solutions of hydrochloric acid and sulfuric acid" @default.
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- W1966756719 doi "https://doi.org/10.1016/0022-1902(67)80264-1" @default.
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