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- W1966756844 abstract "The controlled growth of poly(glycidyl methacrylate) (PGMA) and poly(GMA-co-MMA) brushes by atom transfer radical polymerization (ATRP) in methanol/water has been demonstrated on silicon wafer surfaces. A polymerization system using copper(I) bromide, copper(II) chloride and 2,2′-dipyridyl was found to produce a nearly linear rate of growth for times of up to 4 h, giving brushes of up to 120 nm thickness. Reinitiation of these brushes to grow further PGMA demonstrated the living nature of the polymerization system. A trichlorosilane-functional initiator was used, and it was found that brushes grown from initiator layers deposited in the presence of a small amount of triethylamine were less rough and showed more linear growth with time. The reaction of the pendant epoxide group of these brushes with octylamine from solution was demonstrated." @default.
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- W1966756844 date "2004-01-01" @default.
- W1966756844 modified "2023-10-13" @default.
- W1966756844 title "Controlled growth and subsequent chemical modification of poly(glycidyl methacrylate) brushes on silicon wafers" @default.
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- W1966756844 doi "https://doi.org/10.1039/b312513k" @default.
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