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- W1966775471 abstract "Subsolidus phase relations of ternary oxide systems containing divalent Fe, Mg, or Ni, trivalent Al, Cr, or Fe, and tetravalent Ti are characterized by solid solutions at metal/oxygen ratios 34, 23, and 35. At low temperatures only compounds with cubic or hexagonal close-packed oxygen and uniform oxygen coordination remain stable in the crystal structures NaCl, spinel, ilmenite-α-Al2O3, TiO2. The pseudobrookite phases FeTi2O5, MgTi2O5, Al2TiO5, Fe2TiO5, the V3O5 structure phase Cr2TiO5, and the Andersson phases Cr2Tin−2O2n−1 (n = 4,6,7,8,9) decompose. Additional phases with close-packed oxygen as predicted by a simple structure model for metal/oxygen ratios 712, 56, and 1112 do not form but presumably are important for nonstoichiometric solid solutions. Most differences between systems containing transition metals and the MgOAl2O3TiO2 system can be attributed to crystal field effects." @default.
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- W1966775471 date "1981-01-01" @default.
- W1966775471 modified "2023-09-26" @default.
- W1966775471 title "Crystallography and phase relations of MeOM2O3TiO2 systems (Me = Fe, Mg, Ni; M = Al, Cr, Fe)" @default.
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- W1966775471 doi "https://doi.org/10.1016/0022-4596(81)90191-2" @default.
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