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- W1966783882 abstract "Die Iodcyclopropane 1–6 sind nach dem Makosza-Verfahren leicht erhältlich. Das 1,1-Diiod-cyclopropan 1 reagiert mit Metallorganylen weitgehend unter Ringerhalt. So werden mit Lithium-diorganylcuprat die monosubstituierten Derivate 16a, b, 19, 21 und 23 erhalten. Die Monoiod-cyclopropane 11a bzw. b ergeben mit Lithium-dimethylcuprat unter Retention ausschließlich 26 a bzw. b Mit Metallsalzen wie Silbertosylat und Quecksilberacetat wird 1 geöffnet, und Folgeprodukte des Allyl-Kations A oder des Übergangszustands B werden isoliert. Synthesis and Properties of 1,1-Diiodo- and 1-Iodo-1-x-cyclopropanes The iodocyclopropanes 1–6 are easily obtained by the readily 1 Makosza method. The 1,1-diiodocyclopropane 1 reacts with organometallics preferably without ring cleavage. Thus, with lithium diorganylcuprate the mono-substituted derivatives 16a, b, 19, 21, and 23 are obtained. Reactions of the monoiodocyclopropanes 11a or b with lithium dimethylcuprate yield exclusively 26a and b, resp., with retention. With metal salts such as silver tosylate or mercury acetate 1 is cleaved and products arising via allyl cation A or via transition state B are isolated." @default.
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- W1966783882 title "Darstellung und Eigenschaften von 1,1‐Diiod‐ und 1‐Iod‐1‐x‐cyclopropanen" @default.
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- W1966783882 doi "https://doi.org/10.1002/cber.19791120902" @default.
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