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- W1966794003 abstract "This paper reviews the concepts of electronegativity and ionicity, together with the concept of effective static atomic charge which is associated with them. It is briefly recalled that the ionicity of a chemical bond has two components: a chemical component linked to the valency of the atoms and to their short distance spatial arrangement, and an electrostatic component linked to their effective charge. In solids, however, the appearance of group vibrations of the atoms also introduces the concept of effective dynamic charge, taking account of dielectric phenomena. Emission, absorption, and diffraction of x‐rays are related to these two kinds of effective atomic charges and may be used for evaluating them. The substitution, in the second component of ionicity, of the dynamic charge for the static charge probably defines something different from what is usually called ionicity." @default.
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- W1966794003 date "1977-01-01" @default.
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- W1966794003 title "Electronegativity, Ionicity, and Effective Atomic Charges" @default.
- W1966794003 doi "https://doi.org/10.1149/1.2133237" @default.
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