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• W1966796692 abstract "Abstract Square-planar Pt(II) and octahedral Pt(IV) ionic complexes [H2Me2ppz]2+ [PtCl4]2− (1), [PtCl3(H2Meppz)]2[H2Me2ppz]2+-[PtCl4]2−·2H2O (2) and [H2Me2ppz]2+[PtCl6]2− (3) have been synthesized and their molecular structure and geometry investigated through X-ray diffraction. The N-methylpiperazinium(+1) ligand bound to Pt(II) in complex 2 and the dipositive N,N′-dimethylpiperazinium(+2) cation in complexes 1,2 and 3 are always present in the energetically favoured chair conformation. Moreover the crystals of complex 2 show an unusual situation containing at the same time [PtCl3(H2Meppz)]2 amphiionic molecules and [H2Me2ppz]2+ [PtCl4]2− ions." @default.
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• W1966796692 date "1998-07-01" @default.
• W1966796692 modified "2023-10-03" @default.
• W1966796692 title "Synthesis and molecular structure of N-methylpiperazinium(+1) and N,N′-dimethylpiperazinium(+2) platinum(II) and platinum(IV) complexes Part II" @default.
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• W1966796692 doi "https://doi.org/10.1016/s0020-1693(98)00067-x" @default.
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