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- W1966806581 abstract "The mixture of isomeric dimethyl-endo-tricyclo[5.2.1.02,6]deca-3,8-dienes (A) resulting from Diels-Alder reactions of 1-, 2-, and 5-methylcyclopenta-1,3-dienes (i–iii, respectively) at 20° was shown by GLC analysis to consist of at least 10 components (Table 1). The structures of the six major isomers 1–6, representing 96% of the total mixture, were established by 1H- and 13C-NMR spectroscopy. Whereas on heating up to 110° the proportions of 1, 2, 4, and 6 remain nearly unaffected (±2 %), the dimers 3 and 5, formed in 22 % and 24 % yield, respectively, at 20°, isomerise above 70° reversibly via [3,3]-sigmatropic rearrangement and equilibrate at 110° to a ca. 10:1 ratio." @default.
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- W1966806581 date "1989-09-20" @default.
- W1966806581 modified "2023-10-17" @default.
- W1966806581 title "Structure and Thermal Behaviour of Methylcyclopentadiene Dimers" @default.
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- W1966806581 doi "https://doi.org/10.1002/hlca.19890720623" @default.
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