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• W1966831180 abstract "THiocystine (bis-[2-amino-2-carboxyethyl]trisulfide) is a natural substrate for rhodanese (thiosulfate:cyanide sulfurtransferase, EC 2.8.1.1). Analogs of thiocystine were prepared by eliminating the carboxyl or amino group or by lengthening the carbon chain. Of these only homothiocystine (bis-[2-amino-2-carboxypropyl]trisulfide) had appreciable activity as a substrate. At pH 8.6, the optimum for rhodanese, transfer of sulfane sulfur to cyanide in the presence of rhodanese was nonspecific. Only the sulfane sulfur of 35S-labeled thiocystine was transferred to rhodanese. Thus, thiocystine and thiosulfate both produce a rhodanese persulfide as a stable intermediate in sulfur transfer." @default.
• W1966831180 created "2016-06-24" @default.
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• W1966831180 date "1979-03-01" @default.
• W1966831180 modified "2023-09-23" @default.
• W1966831180 title "Transfer of persulfide sulfur from thiocystine to rhodanese" @default.
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• W1966831180 doi "https://doi.org/10.1016/0005-2744(79)90180-3" @default.
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