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- W1966836699 abstract "Ru–vinylidene complexes, Cl2Ru{CC(H)tBut}(PCy3)(L) (L=PCy3 or N-heterocyclic carbenes) reveal themselves as a versatile catalyst for the atom transfer radical addition (ATRA) of polyhalogenated alkanes to olefins, such as methylmethacrylate, styrene and 1-octene. Furthermore, these systems are excellent catalysts for the nucleophilic addition of carboxylic acids to terminal alkynes and yielded exclusively alk-1-en-2-yl esters. These complexes can also be transformed to their cationic counterparts by treating the neutral complexes with AgBF4 and their catalytic potential in ATRA and vinylation reaction are investigated." @default.
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- W1966836699 date "2002-12-01" @default.
- W1966836699 modified "2023-10-18" @default.
- W1966836699 title "Atom transfer radical addition and enol-ester synthesis catalyzed by Ru–vinylidene complexes" @default.
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- W1966836699 doi "https://doi.org/10.1016/s0040-4039(02)02233-5" @default.
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