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- W1966852218 abstract "1. G.l.c.-mass spectral analysis of t.l.c. fractions of urine samples of patients treated with 5-(2-chloroethyl)-4-methylthiazole (clomethiazole), has revealed two minor metabolites, each with two sulphur atoms.2. Their structures were found to be 2-methylthio-clomethiazole and 5-acetyl-4-methyl-2-mercapto-thiazole, formed by thiomethylation and thiohydroxylation, respectively, of the original compound.3. The structures of six other minor metabolites resulting from side-chain degradation have been elucidated.4. The occurrence of metabolites with substituents at position 2 of the heterocyclic nucleus is assumed to be initiated by oxidative attack at the nitrogen, followed by nucleophilic substitution in position 2." @default.
- W1966852218 created "2016-06-24" @default.
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- W1966852218 date "1982-01-01" @default.
- W1966852218 modified "2023-09-25" @default.
- W1966852218 title "Thiomethylation and thiohydroxylation –a new pathway of metabolism of heterocyclic compounds" @default.
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- W1966852218 doi "https://doi.org/10.3109/00498258209038953" @default.
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