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- W1966854906 abstract "Copolymers of ε-caprolactone (CL) and trimethylene carbonate (TMC) have been synthesized through ring-opening polymerization using a novel initiator of scandium tris(2,6-di-tert-butyl-4-methylphenolate). CL and TMC polymerizations proceed via the “coordination anionic mechanism” with acyl−oxygen bond cleavage. Five kinds of copolymers with different structures of X, XB, AXB, AB, and BAXB are synthesized under different polymerization conditions and characterized by 1H NMR, GPC, and DSC, where X, A, and B denote as random blocks of CL and TMC, PTMC blocks, and PCL blocks, respectively." @default.
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- W1966854906 date "2004-01-15" @default.
- W1966854906 modified "2023-09-25" @default.
- W1966854906 title "Controlling Ring-Opening Copolymerization of ε-Caprolactone with Trimethylene Carbonate by Scandium Tris(2,6-di-<i>tert</i>-butyl-4-methylphenolate)" @default.
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- W1966854906 doi "https://doi.org/10.1021/ma035352f" @default.
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