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- W1966869277 abstract "A practical method for (S)-p-methoxyhomophenylalanine (S)-1 by using diastereoselective Michael addition as a key step was reported. Thus, the Michael addition of (S)-1-phenethylamine (S)-3 to p-methoxy-trans-benzoylacrylic acid 2 was performed in a highly stereoselective (up to 98% d.e. and up to 90% yield) fashion and, subsequently, the resultant adduct 4a was catalytically hydrogenated to afford (S)-1 almost quantitatively. The most likely mechanism of the addition reaction was dynamic resolution." @default.
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- W1966869277 date "1998-12-01" @default.
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- W1966869277 title "A highly efficient asymmetric synthesis of methoxyhomophenylalanine using michael addition of phenethylamine" @default.
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- W1966869277 doi "https://doi.org/10.1016/s0040-4039(98)02023-1" @default.
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