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- W1966890513 abstract "The behavior of the 2-acetamido-1-N-(l-aspart-4-oyl)-deoxy-β-d-glucopyranosyl residue during sequential hydrazinolysis, N-reacetylation, reduction, and methylation analysis was investigated in the model compounds, β-d-Galp-(1→4)-β-d-GlcpNAc-(1→4)-Asn, α-d-Manp-(1→6)-β-d-Manp-(1→4)-β-d-GlcpNAc-(1→4)-β-d-GlcpNAc-(1→4)-Asn, and α-d-Manp-(1→6)-β-d-Manp-(1→4)-β-d-GlcpNAc-(1→4)-[α-l-Fucp-(1→6)]-β-d-GlcpNAc-(1→4)-Asn. The products from the reaction were partly separated, and gas—liquid chromatography—mass spectrometry and fast-atom-bombardment mass spectrometry indicated the presence of 8 by-products in addition to 2-acetamido-2-deoxyglucitol derivatives. It is postulated that these by-products are formed by a series of kinetically competitive processes starting from the key intermediate, 2-acetamido-2-deoxy-d-glucose hydrazone." @default.
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- W1966890513 date "1984-12-01" @default.
- W1966890513 modified "2023-10-17" @default.
- W1966890513 title "Behavior of the 2-acetamido-2-deoxy-α-d-glucopyranosyl residue during sequential hydrazinolysis, N-reacetylation, reduction, and methylation of glycoasparagines" @default.
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- W1966890513 doi "https://doi.org/10.1016/0008-6215(84)85036-3" @default.
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