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- W1966890711 abstract "C3-symmetrical tris-urea low molecular weight gelator 1 was synthesized in three steps from phloroglucin. The gelation ability of 1 in four chloroalkanes, i.e., CH2Cl2, CHCl3, 1,1,2-trichloroethane, and 1,1,2,2-tetrachloroethane, was investigated under various conditions. Thermal treatment was effective in gelating 1,1,2-trichloroethane. In the presence of equimolar 1 and CuBr2, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane formed gels. Mixtures of 1 and CHCl3 or 1,1,2,2-tetrachloroethane gave gels after ultrasound irradiation. CH2Cl2 changed into a gel in the presence of equimolar 1 and BiCl3 after sonication. Spherical particles with rough surfaces were found by SEM observation of CHCl3 gel prepared from ultrasound irradiation of 1 and Y(NO3)3." @default.
- W1966890711 created "2016-06-24" @default.
- W1966890711 creator A5012235399 @default.
- W1966890711 creator A5027801877 @default.
- W1966890711 date "2009-06-24" @default.
- W1966890711 modified "2023-10-03" @default.
- W1966890711 title "Chloroalkane Gel Formations by Tris-urea Low Molecular Weight Gelator under Various Conditions" @default.
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- W1966890711 doi "https://doi.org/10.1021/jo900894q" @default.
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