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• W1966895972 endingPage "7516" @default.
• W1966895972 startingPage "7513" @default.
• W1966895972 abstract "Hybrid films composed of chitosan and Keplerate-type polyoxometalate, {Mo72Fe30} (Mo72VIFe30IIIO252L102·ca.180H2O, L = H2O/CH3COO−/Mo2O8/9n−), were fabricated on quartz, silicon, and ITO substrates by layer-by-layer (LbL) method. The LbL films were characterized by UV−vis spectroscopy, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and cyclic voltammetry (CV). UV−vis spectra show that the absorbance values at characteristic wavelengths of the multilayer films increase almost linearly with the number of chitosan/{Mo72Fe30} bilayers. XPS spectra confirm the incorporation of chitosan and {Mo72Fe30} into the films. The electrocatalytic reduction of ClO3−, BrO3−, and IO3− by chitosan/{Mo72Fe30} hybrid films in an acidic aqueous solution shows an electrocatalytic reduction activity of IO3− > BrO3− > ClO3−. In particular, the modified electrodes exhibited high electrocatalytic activity for reduction of IO3−." @default.
• W1966895972 created "2016-06-24" @default.
• W1966895972 creator A5048752088 @default.
• W1966895972 creator A5081628033 @default.
• W1966895972 date "2009-04-30" @default.
• W1966895972 modified "2023-10-11" @default.
• W1966895972 title "Fabrication and Electrocatalytic Properties of Chitosan and Keplerate-Type Polyoxometalate {Mo₇₂Fe₃₀} Hybrid Films" @default.
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• W1966895972 doi "https://doi.org/10.1021/jp901413w" @default.
• W1966895972 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19405489" @default.
• W1966895972 hasPublicationYear "2009" @default.
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