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- W1966896797 abstract "Electrochemical reactions of cyanocobalaminn, CNCbl[Co(III)], were studied at glassy carbon electrodes in acidic media by means of cyclic voltammetry and differential pulse polarography. It was found that in pH 0 solution, CNCbl[Co(III)] exists mainly in the base-off form, {CNCbl[Co(III)]}base-off. It can undergo a one-electron reduction and a follow-up chemical reaction to form {H2OCbl[Co(II)]}base-off. The rate-constant k of the follow-up decyanation reaction is 0.022s−1. {H2OCbl[Co(II)]}base-off is further reduced obtain H2OCbl[Co(I)]." @default.
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- W1966896797 date "1997-05-01" @default.
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- W1966896797 title "Electrochemical reactions of cyanocobalamin in acidic media" @default.
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