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• W1966913141 abstract "An integrated atomic force and polarized Raman microscope were used to measure the elastic properties of individual diphenylalanine (FF) nano- and micro-tubes and to obtain quantitative information regarding the inter-molecular interactions that define their mechanical properties. For individual tubes, co-localised force spectroscopy and Raman spectroscopy measurements allowed the calculation of the Young's and shear moduli (25 ± 5 GPa and 0.28 ± 0.05 GPa, respectively) and the contribution of hydrogen bonding network to the Young's modulus (∼17.6 GPa). The π-π interactions between the phenyl rings, dominated by T-type arrangements, were estimated based on previously published X-ray data to only 0.20 GPa. These results provide experimental evidence obtained from individual FF tubes that the network of H-bonds dominates the elastic properties of the FF tubes." @default.
• W1966913141 created "2016-06-24" @default.
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• W1966913141 date "2014-06-23" @default.
• W1966913141 modified "2023-09-25" @default.
• W1966913141 title "Co-localised Raman and force spectroscopy reveal the roles of hydrogen bonds and π-π interactions in defining the mechanical properties of diphenylalanine nano- and micro-tubes" @default.
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• W1966913141 doi "https://doi.org/10.1063/1.4885090" @default.
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